Organocatalytic asymmetric conjugate addition and cascade acyl transfer reaction of α-nitroketones
Organocatalytic asymmetric conjugate addition of α-nitroketones to β,γ-unsaturated α-keto esters has been developed. A pyrrolidine-based thiourea-tertiary amine was identified as the best catalyst. The reaction was found to proceed via cascade conjugate a
Lu, Rui-Jiong,Yan, Yun-Yun,Wang, Jin-Jia,Du, Quan-Sheng,Nie, Shao-Zhen,Yan, Ming
experimental part
p. 6230 - 6239
(2011/10/04)
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