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131470-66-1

2-(TRIBUTYLSTANNYL)-5,6-DIHYDRO-[1,4]-DIOXIN, also known as TBDOG, is a chemical compound that features a dioxin ring with a tributylstannyl group attached. 2-(TRIBUTYLSTANNYL)-5,6-DIHYDRO-[1,4]-DIOXIN is widely recognized for its versatility in organic chemistry, particularly in the synthesis of intricate organic molecules. Its capacity to engage in a range of reactions, including cross-coupling, cyclization, and carbon-carbon bond formation, makes it a valuable reagent. Additionally, it serves as a precursor in the creation of pharmaceuticals, agrochemicals, and materials for scientific applications. Despite its utility, TBDOG is acknowledged to possess toxicity and potential environmental hazards, necessitating stringent control and management in its application.

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  • 131470-66-1 Structure

  • Basic information

    1. Product Name: 2-(TRIBUTYLSTANNYL)-5,6-DIHYDRO-[1,4]-DIOXIN
    2. Synonyms: 2-TRIBUTYLSTANNYLDIOXENE;2-(TRIBUTYLSTANNYL)-5,6-DIHYDRO-[1,4]-DIOXIN;Tributyl(5,6-dihydro-1,4-dioxin-2-yl)stannane
    3. CAS NO:131470-66-1
    4. Molecular Formula: C16H32O2Sn
    5. Molecular Weight: 375.13
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 131470-66-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 354.2 °C at 760 mmHg
    3. Flash Point: 168 °C
    4. Appearance: /
    5. Density: N/A
    6. Vapor Pressure: 6.94E-05mmHg at 25°C
    7. Refractive Index: N/A
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: 2-(TRIBUTYLSTANNYL)-5,6-DIHYDRO-[1,4]-DIOXIN(CAS DataBase Reference)
    11. NIST Chemistry Reference: 2-(TRIBUTYLSTANNYL)-5,6-DIHYDRO-[1,4]-DIOXIN(131470-66-1)
    12. EPA Substance Registry System: 2-(TRIBUTYLSTANNYL)-5,6-DIHYDRO-[1,4]-DIOXIN(131470-66-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 131470-66-1(Hazardous Substances Data)

131470-66-1 Usage

Uses

Used in Organic Chemistry:
2-(TRIBUTYLSTANNYL)-5,6-DIHYDRO-[1,4]-DIOXIN is used as a reagent for its ability to participate in various chemical reactions such as cross-coupling, cyclization, and carbon-carbon bond formation, which are essential for the synthesis of complex organic molecules.
Used in Pharmaceutical Synthesis:
In the pharmaceutical industry, 2-(TRIBUTYLSTANNYL)-5,6-DIHYDRO-[1,4]-DIOXIN is used as a precursor in the development of new drugs, contributing to the creation of molecules with potential therapeutic applications.
Used in Agrochemical Development:
2-(TRIBUTYLSTANNYL)-5,6-DIHYDRO-[1,4]-DIOXIN is utilized as a starting material in the synthesis of agrochemicals, playing a role in the production of compounds designed to enhance crop protection and yield.
Used in Materials Science:
Within the field of materials science, 2-(TRIBUTYLSTANNYL)-5,6-DIHYDRO-[1,4]-DIOXIN is employed as a component in the synthesis of advanced materials, potentially contributing to the development of new technologies and products with specific properties.

Check Digit Verification of cas no

The CAS Registry Mumber 131470-66-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,1,4,7 and 0 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 131470-66:
(8*1)+(7*3)+(6*1)+(5*4)+(4*7)+(3*0)+(2*6)+(1*6)=101
101 % 10 = 1
So 131470-66-1 is a valid CAS Registry Number.
InChI:InChI=1/C4H5O2.3C4H9.Sn/c1-2-6-4-3-5-1;3*1-3-4-2;/h1H,3-4H2;3*1,3-4H2,2H3;/rC16H32O2Sn/c1-4-7-12-19(13-8-5-2,14-9-6-3)16-15-17-10-11-18-16/h15H,4-14H2,1-3H3

131470-66-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name tributyl(2,3-dihydro-1,4-dioxin-5-yl)stannane

1.2 Other means of identification

Product number -
Other names dioxenyltri-n-butylstannane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:131470-66-1 SDS

131470-66-1Relevant articles and documents

Total Synthesis of Epicolactone

Kravina, Alberto G.,Carreira, Erick M.

supporting information, p. 13159 - 13162 (2018/09/21)

The biologically active and structurally complex secondary metabolite epicolactone is a member of the natural product pool found in cash crop endophytes of the genus Epicoccum. By exploiting inherent reactivity, a total synthesis of this highly oxygenated

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