Synthesis of organophosphorus compounds via silyl esters of phosphorous acids
The addition of trimethylsilyloxy phosphorus (III)derivatives generated in situ to imines at room temperature provides a mild selective and high yielding route to α-aminoalkylphosphorate and α-aminoalkylphenylphosphinate esters. Isocyanates and carbodiimides react similarly to give phosphonoureas and phosphonoguarnidines respectively aldehydes and ketones are much less reactive and cyanides are inert.
Afarinkia, Kamyar,Rees, Charles W.,Cadogan, John I. G.
p. 7175 - 7196
(2007/10/02)
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