Sulfenate substitution as a complement and alternative to sulfoxidation in the diastereoselective preparation of chiral β-substituted β-amino sulfoxides
Building from a previous communication, the reaction of sulfenate anions with chiral N-Boc-protected β-substituted β-amino iodides was evaluated as a conceptually different synthetic approach to chiral β-substituted β-amino sulfoxides. Using arenesulfenat
S?derman, Stefan C.,Schwan, Adrian L.
p. 1638 - 1649
(2013/03/28)
The diastereoselective alkylation of arenesulfenate anions using homochiral electrophiles
A series of Boc-protected β-amino sulfoxides were prepared by the reaction of arenesulfenate anions with chiral Boc-protected β-amino iodides. The stereoselective substitution reaction is believed to arise through precoordination of the sulfenate counteri
Soederman, Stefan C.,Schwan, Adrian L.
p. 4192 - 4195
(2011/10/08)
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