- Action of Alkali on O-Benzylated Aldoses: A Simple Rationalization of Some Reactions Occurring in Alkaline Media
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Treatment of some O-benzyl-protected aldopyranoses and aldofuranoses with sodium 2-propoxide or K2CO3 brought about their equilibration and the loss of the elements of benzyl alcohol, with concomitant formation of a Z aldehyde.The latter rearranged rapidl
- Anastasia, Mario,Allevi, Pietro,Ciuffreda, Pierangela,Fiecchi, Alberto,Scala, Antonio
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p. 3054 - 3058
(2007/10/02)
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- Boron Enolates in Stereoselective Syntheses of 2-Enitols from O-Benzyl Aldoses by Reaction with Borohydride in 2-Propanol. Configuration of E and Z Enols from Proton Relaxation Rates
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Isomerically pure E and Z forms of 2,4,6-tri-O-benzyl-2-dehydro-3-deoxy-D-erythro-hex-2-enitol (4 and 3, respectively) were synthesized from 2,3,4,6-tetra-O-benzyl-D-glucopyranose by reactions employing sodium borohydride and 2-propanol under differing co
- Rao, Vanga S.,Perlin, Arthur S.
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p. 3265 - 3269
(2007/10/02)
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