A ligand-conformation driving chiral generation and symmetry-breaking crystallization of a zinc(ii) organoarsonate
An unusual ligand-conformation driving chiral generation and symmetry-breaking crystallization occurred simultaneously in the formation of a layered zinc(ii) arsonate Zn(Hcapa)(4,4′-bipy) (1P) and its enantiomorph (1M) without any chiral sources, indicati