A convenient preparation of N-alkyl and N-arylamines by smiles rearrangement - Synthesis of analogues of diclofenac
Smiles rearrangement of substituted aryloxyacetamides in which oxygen and nitrogen are separated by COCH2 group has been successful even when the aryloxy ring carries weak or no electron withdrawing group. Earlier reports of such reactions involved either strong electron withdrawing groups or a special catalyst. The diphenylamines thus obtained gave analogues of diclofenac in only one case.
Wadia,Patil
p. 2725 - 2736
(2007/10/03)
N,N'-Diphenylphosphorodiamido Chloridate, a Novel Reagent for the Synthesis of Anilides
N,N'-Diphenylphosphorodiamido chloridate (I) is found to be a suitable reagent for the synthesis of anilides (II) of carboxylic acids.A plausible reaction mechanism has been proposed.
Parkhe, Anil B.,Bhai, Aziz,Porwal, K. K.,Boparai, K. S.
p. 79 - 80
(2007/10/02)
Studies on herbicides and plant growth regulators. II. Synthesis and some reactions of 1-aryloxyacylpyrazoles.
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Ochiai,Kamikado
p. 628 - 641
(2007/10/04)
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