Highly enantioselective intermolecular stetter reactions of β-aryl acceptors: α-ketoester moiety as handle for activation and synthetic manipulations
The use of β,γ-unsaturated-α-ketoesters in the intermolecular Stetter reaction furnishes 1,2,5-tricarbonyl compounds in high yield and excellent enantioselectivity. The α,δ-diketoesters generated using this methodology serve as useful synthetic building b
Sanchez-Larios, Eduardo,Thai, Karen,Bilodeau, Francois,Gravel, Michel
p. 4942 - 4945
(2011/11/29)
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