Stereochemical studies on Esperamicins: Determination of the absolute configuration of hydroxyamino sugar fragment
The β-D-gluco-hexopyranose configuration has been assigned for the hydroxyamino sugar fragment or esperamicin A. This determination concluded our study on the absolute configuration of the carbohydrate portion of esperamicins.
Golik,Wong,Krishnan,Vyas,Doyle
p. 1851 - 1854
(2007/10/02)
Synthesis of 4-deoxy and 4-deoxy-4-halogeno derivatives of L-fucose as potential enzyme inhibitors
Methyl-2,3-di-O-benzoyl-6-deoxy-α-L-galactopyranoside (2) was converted into the 4-deoxy-4-iodo-α-L-gluco derivative 4 by triflate-mediated inversion.Catalytic reduction of 4 gave methyl 2,3-di-O-benzoyl-4,6-dideoxy-α-L-xylo-hexopyranoside (6) and subsequ
Lindhorst, Thisbe K.,Thiem, Joachim
p. 119 - 129
(2007/10/02)
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