Rate and Equilibrium Constants of Dimethylcarbamoyl Transfer between Pyridine N-Oxides
Dimethylcarbamoyl transfer from N-acyloxypyridinium salts to pyridine N-oxides in acetonitrile occurs in one stage by the forced concerted SN2 mechanism. The rate and equilibrium of the reaction are fairly described by the Bronsted equation. The Marcus equation provides a much higher quality of reactivity predictions.
Intramolecular charge transfer processes in a series of styryl derivatives of pyridine and quinoline N-oxides
Intramolecular charge transfer processes in a series of the trans-isomers of styryl derivatives of pyridines and quinolines, their hydrochlorides and molecular complexes with BF3 have been studied by electronic and IR spectroscopy. Electron don
Andreev,Batotsyrenova,Ryzhakov,Rodina
p. 941 - 949
(2007/10/03)
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