A cyclohexane pro-ionophore is held in one chair form (non-ionophoric) by a large, tertiary, ketal moiety.Upon hydrolysis the acetyl group is small enough to be axial and the cyclohexane ring can flip to an ionophoric conformation.
Raban, Morton,Quin, John,Belguise, Alain
p. 35 - 38
(2007/10/02)
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