Kinetic resolution of racemic alcohols with chiral carboxylic acids and dicyclohexylcarbodiimide
The DCC-esterification method has been used to kinetically resolve racemic mixtures of alcohols. With simple chiral carboxylic acids, such as O-aryl lactic acids, in the presence of various basic catalysts, mixtures of the enantiomerically enriched alcohols (e.e. 50%) and the corresponding esters (d.e. 70%) have been obtained.
Chinchilla,Najera,Yus,Heumann
p. 851 - 854
(2007/10/02)
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