13393-68-5

Basic information

• Product Name: t-Hexyl hydroperoxide
• Synonyms: t-Hexyl hydroperoxide;1,1-Dimethylbutyl hydroperoxide
• CAS NO: 13393-68-5
• Molecular Formula: C₆H₁₄O₂
• Molecular Weight: 118.17416
• Mol File: 13393-68-5.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: t-Hexyl hydroperoxide(CAS DataBase Reference)
• NIST Chemistry Reference: t-Hexyl hydroperoxide(13393-68-5)
• EPA Substance Registry System: t-Hexyl hydroperoxide(13393-68-5)

Safety Data

• Hazardous Substances Data: 13393-68-5(Hazardous Substances Data)

Usage

Uses

Used in Polymer Production:
t-Hexyl hydroperoxide is utilized as a radical initiator in the manufacturing process of polymers. Its reactivity aids in the polymerization process, which is essential for producing a wide range of polymer-based materials.
Used in Oxidation Reactions:
In chemical synthesis, t-Hexyl hydroperoxide serves as a key component in certain oxidation reactions. Its role as an oxidizing agent helps drive the reactions to completion, facilitating the production of desired oxidized compounds.
Used in Synthetic Rubber Manufacturing:
t-Hexyl hydroperoxide is employed as a crosslinking agent in the production of synthetic rubber. Its ability to form crosslinks between polymer chains contributes to the rubber's strength, elasticity, and overall performance characteristics.
Used in Pharmaceutical Synthesis:
As an intermediate in the synthesis of pharmaceuticals, t-Hexyl hydroperoxide plays a crucial role in the development of various organic compounds used in the production of medications.
Used in Organic Compound Synthesis:
Beyond pharmaceuticals, t-Hexyl hydroperoxide is also used as an intermediate in the synthesis of other organic compounds, highlighting its versatility in chemical reactions.

Upstream product

• 107-83-5 2-Methylpentane 
• 590-36-3 2-methylpentan-2-ol 

Downstream Products

• 28509-29-7 β-(2-Methylpent-2-ylperoxy)-aethylsulfonsaeurephenylester 
• 20743-49-1 2-methyl-5-phenyl-2H-tetrazole 
• 22743-71-1 1,1-di(tert-hexylperoxy)cyclohexane 
• 118364-97-9 2-(n-propyl)-2-propyl peroxypivalate 

Relevant articles and documents

New route for conversion of camptothecin to 7-ethylcamptothecin and 7-propylcamptothecin

In this article, a new route for conversion of camptothecin to 7-ethylcamptothecin and 7-propylcamptothecin is described. Compared with previous reports, the reaction time of the new synthetic route was greatly shortened to 30 min, and the products were obtained in high yield. Copyright Taylor & Francis Group, LLC.

Oxidations by the reagent "O2-H2O2-vanadium derivative-pyrazine-2-carboxylic acid". Part 12. Main features, kinetics and mechanism of alkane hydroperoxidation

Various combinations of vanadium derivatives (n-Bu4NVO3 is the best catalyst) with pyrazine-2-carboxylic acid (PCA) catalyse the oxidation of saturated hydrocarbons, RH, with hydrogen peroxide and air in acetonitrile solution to produce, at temperatures V(PCA)(H2O2) → VIV(PCA) + HOO. + H+. The VIV species thus formed reacts further with a second H2O2 molecule to generate the hydroxyl radical according to the equation VIV(PCA) + H2O2 → VV(PCA) + HO. + HO-. The concentration of the active species in the course of the catalytic process has been estimated to be as low as [V(PCA)H2O2] ≈ 3.3 × 10-6 mol dm-3. The effective rate constant for the cyclohexane oxidation (d[ROOH]/dt = keff[H2O2]0[V]0) is keff = 0.44 dm3 mol-1 s-1 at 40 °C, the effective activation energy is 17 ± 2 kcal mol-1. It is assumed that the accelerating role of PCA is due to its facilitating the proton transfer between the oxo and hydroxy ligands of the vanadium complex on the one hand and molecules of hydrogen peroxide and water on the other hand. For example: (pca)(O=)V ... H2O2 → (pca)(HO-)V-OOH. Such a "robot's arm mechanism" has analogies in enzyme catalysis.