Chiral allene-containing phosphines in asymmetric catalysis
We demonstrate that allenes, chiral 1,2-dienes, appended with basic functionality can serve as ligands for transition metals. We describe an allene-containing bisphosphine that, when coordinated to Rh(I), promotes the asymmetric addition of arylboronic ac
Cai, Feng,Pu, Xiaotao,Qi, Xiangbing,Lynch, Vincent,Radha, Akella,Ready, Joseph M.
supporting information; experimental part
p. 18066 - 18069
(2012/01/04)
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