Mass Spectral Fragmentations and Gas Phase Reactions of t-Butyl Peresters
The mass spectral behaviour of a few aliphatic and aromatic peresters has been studied under electron impact (EI) and chemical ionization (CI) conditions.Under EI, fragmentation of the molecules occurs mainly by C-C cleavage at either side of the carbonyl group.The C4H9O+ ion generated by the attack of the CI reagent on the sample molecule adds on to the molecule leading to (M + 73)+ ion in the CI (i-C4H10) spectra while with the more basic reagent, NH3, clustering of the molecule around NH4+ ion is the predominant pathway for ion formation.
Madhusudanan, K. P.,Misra, Dharmendra,Singh, Chandan
p. 398 - 401
(2007/10/02)
TRANSFORMATION OF HIGHER α-DIKETONES UNDER THE INFLUENCE OF SOME PEROXIDE PRODUCTS FROM THE OXIDATION OF ALKANES
-
Gol'dman, O. V.,Perkel', A. L.,Smirnova, T. Ya.,Freidin, B. G.
p. 1694 - 1699
(2007/10/02)
More Articles about upstream products of 13467-82-8