- Palladium-Catalyzed Germylation of Organic Halides with a Digermane. Unexpected Formation of Germylene-Insertion Type Products
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Organic halides (RX) underwent dehalogenative germylation and germylene insertion type reactions with ClMe2GeGeMe2Cl in the presence of Pd(PPh3)4 as catalyst to give RGeMe2Cl and RGeMe2X respectively.
- Reddy, Prabhakar N.,Hayashi, Teruyuki,Tanaka, Masato
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p. 677 - 680
(2007/10/02)
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- Double Germylation of Unsaturated Carbon Compounds with Digermanes in the Presence of Palladium and Platinum Catalysts
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Double germylation of acetylenes, isoprene, and ethylene with 1,2-dichloro-1,1,2,2-tetramethyldigermane proceeds in the presence of palladium- and platinum-phosphorus ligand complexes to afford α,ω-bis(chlorodimethylgermyl) compounds in moderate to good yields.
- Hayashi, Teruyuki,Yamashita, Hiroshi,Sakakura, Toshiyasu,Uchimaru, Yuko,Tanaka, Masato
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p. 245 - 248
(2007/10/02)
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