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134698-86-5

Muricatacin, also known by various other names including (-)-(4R,5R)-Muricatacin and (R,R)-Muricatacin, is an enantiomerically pure compound that serves as a key chiral building block in organic synthesis. It is particularly valuable in the construction of complex natural products, such as annonaceous acetogenins, due to its stereochemical integrity and functional versatility. In the context of the synthesis of (+)-4-deoxygigantecin, muricatacin was utilized as a starting material to achieve the desired stereochemistry and structural framework, underscoring its importance in the preparation of biologically active molecules.

134698-86-5

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134698-86-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 134698-86-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,4,6,9 and 8 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 134698-86:
(8*1)+(7*3)+(6*4)+(5*6)+(4*9)+(3*8)+(2*8)+(1*6)=165
165 % 10 = 5
So 134698-86-5 is a valid CAS Registry Number.
InChI:InChI=1/C17H32O3/c1-2-3-4-5-6-7-8-9-10-11-12-15(18)16-13-14-17(19)20-16/h15-16,18H,2-14H2,1H3/t15-,16-/m1/s1

134698-86-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name (5R)-5-[(1R)-1-hydroxytridecyl]oxolan-2-one

1.2 Other means of identification

Product number -
Other names (1'R,5R)-5-(1'-hydroxytridecanyl)-3H,5H-furan-2-one

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:134698-86-5 SDS

134698-86-5Upstream product

134698-86-5Relevant articles and documents

De novo asymmetric syntheses of muricatacin and its analogues via dihydroxylation of dienoates

Ahmed, Md. Moinuddin,Cui, Hu,O'Doherty, George A.

, p. 6686 - 6689 (2007/10/03)

A short and highly efficient route to both enantiomers of muricatacin as well as the C-5-epimer has been developed. The key to the overall transformation is the highly regio- and enantioselective Sharpless asymmetric dihydroxylation of an (E,Z)-dienoate. The highly efficient stereoselective synthesis prepares (-)-muricatacin in seven steps and 66% overall yield.

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