- Direct addition of Zr-C bonds of alkylzirconocenes to activated alkenes
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Direct addition of alkylzirconocenes to activated alkenes was found, for the first time. Octyl- and decylzirconocene chloride reacted with benzylidenemalononitrile to give the corresponding addition products after hydrolysis in 86% and 79% yield, respecti
- Liu, Yuanhong,Shen, Baojian,Kotora, Martin,Nakajima, Kiyohiko,Takahashi, Tamotsu
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- Iron-Catalyzed Photoredox Functionalization of Methane and Heavier Gaseous Alkanes: Scope, Kinetics, and Computational Studies
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Herein, we report the development of the photocatalytic C-H functionalization of methane, ethane, and heavier gaseous alkanes with good yields and selectivity, broad scope (57 examples), mild conditions, and low cost. Kinetics and density functional theor
- Zhang, Qingqing,Liu, Shuyang,Lei, Jinglan,Zhang, Yongqiang,Meng, Changgong,Duan, Chunying,Jin, Yunhe
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p. 1901 - 1906
(2022/03/27)
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- A Novel Photoalkylation of Electron-deficient Alkenes by Use of Organotin Compounds via Photoinduced Electron Transfer
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Irradiation of 1-aryl-2,2-dicyanoethenes and tetraalkylstannanes in propionitrile in the presence of phenanthrene afforded regioselectively 1-alkyl-1-aryl-2,2-dicyanoethanes in good yields.
- Mizuno, Kazuhiko,Nakanishi, Kazuhisa,Tachibana, Atsushi,Otsuji, Yoshio
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p. 344 - 345
(2007/10/02)
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