OXIDATIVE ADDITION OF HYDROXIDE ANIONS TO NITROALKENES VIA THE RADICAL ANIONS OF α-NITRO-OXIRANES
Stereoselective oxidative addition of hydroxide anions to nitroalkenes was carried out using potassium ferricyanide to yield α-nitro-oxiranes by a novel non-chain mechanism involving cyclisation of alkoxide anions onto α-nitroalkyl radicals.
Bowman, W. Russel,Brown, David S.,Chaffin, Julie D. E.,Symons, Martyn C. R.,Jackson, Stuart W.,Willcocks, Neil A.
p. 2285 - 2288
(2007/10/02)
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