Radical-based regioselective C-H functionalization of electron-deficient heteroarenes: Scope, tunability, and predictability
Radical addition processes can be ideally suited for the direct functionalization of heteroaromatic bases, yet these processes are only sparsely used due to the perception of poor or unreliable control of regiochemistry. A systematic investigation of fact
O'Hara, Fionn,Blackmond, Donna G.,Baran, Phil S.
supporting information
p. 12122 - 12134
(2013/09/02)
Homolytic Alkylations of Substituted Pyridazines
The unsymmetrically substituted pyridazines 1 (X = Ph, CH3) have been found to undergo homolytic heteroaromatic alkylation in moderate to good yields with high regioselectivity.The site of substitution was established by conversion to 5 and measurement of
Samaritoni, Jack G.,Babbitt, George
p. 583 - 587
(2007/10/02)
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