Catalytic Dehydrogenation of Amine-Boranes using Geminal Phosphino-Boranes
The reaction of the intramolecular frustrated Lewis pair (FLP) tBu2PCH2BPh2 with the amine-boranes NH3·BH3 and Me2NH·BH3 leads to the formation of the corresponding FLP-H2/
Boom, Devin H. A.,de Boed, Ewoud J. J.,Nicolas, Emmanuel,Nieger, Martin,Ehlers, Andreas W.,Jupp, Andrew R.,Slootweg, J. Chris
p. 586 - 592
(2020/02/11)
Preorganized frustrated lewis pairs
Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu2PCH 2BPh2 with H2, CO2, and isocyanates and supported computationally.
Bertini, Federica,Lyaskovskyy, Volodymyr,Timmer, Brian J. J.,De Kanter, Frans J. J.,Lutz, Martin,Ehlers, Andreas W.,Slootweg, J. Chris,Lammertsma, Koop
p. 201 - 204
(2012/03/07)
More Articles about upstream products of 1353248-56-2