Evidence for pericyclic and stepwise processes in the cyclodimerization of chloroprene and 1,3-butadiene from pressure dependence and stereochemistry. Experimental and theoretical volumes of activation and reaction
From the pressure dependence of cyclodimerization of chloroprene, it has been concluded that volumes of activation may be useful for the distinction between competing concerted and stepwise cycloadditions. Accordingly, one of the [4 + 2] cyclodimers, 1,4-
Kl?rner, Frank-Gerrit,Krawczyk, Bernd,Ruster, Volker,Deiters, Ulrich K.
p. 7646 - 7657
(2007/10/02)
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