Synthesis of 6-substituted 6-nitroperhydro-1,4-diazepines via novel tandem retro-Henry and Mannich/Michael reactions
N,N′-Dibenzyl-6-hydroxymethyl-6-nitroperhydro-1,4-diazepine was converted into a nitronate via retro-Henry reaction, followed by either Michael reaction with several acrylic derivatives or Mannich reaction with different amines, thus leading to 6-substitu
Martinelli, Jonathan,Gugliotta, Giuseppe,Tei, Lorenzo
supporting information; experimental part
p. 716 - 719
(2012/04/17)
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