Catalytic Aminomercuration Reactions of 3-Alken-1-ynes: An Improved Method for the Synthesis of 2-Amino-1,3-butadienes and 1-Aza-1,3-butadienes
Catalytic aminomercuration of 3-alken-1-ynes leads to 1-aza-1,3-butadienes and 2-amino-1,3-butadienes.Under appropriate reaction conditions it is possible to prepare these compounds via mercuration of 3-alken-1-ynes in the presence of either aromatic or a