'Hemilabile' silyl pincer ligation: Platinum group PSiN complexes and triple C-H activation to form a (PSiC)Ru carbene complex
The first example of PSiN mixed-donor silyl pincer ligation is described. Studies involving platinum group metal complexes of [(2-tBu 2PC6H4)(2-Me2NC6H 4)SiMe]- (tBu-PSiN-Me) confirmed that the ligand amino donor is labile. Within the coordination sphere of Ru, tBu-PSiN-Me is transformed into a PSiC ligand via multiple C-H bond activation events. The Royal Society of Chemistry 2012.
Ruddy, Adam J.,Mitton, Samuel J.,McDonald, Robert,Turculet, Laura
supporting information; experimental part
p. 1159 - 1161
(2012/03/08)
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