Mg-Cu bimetal system for selective C-F bond activation
Bimetal system of Mg-CuCl in DMI for selective C-F and C-Cl bonds activation has been examined. This article involves (1) a short overview of bimetal system of Mg-metals for selective C-F bond activation, (2) C-F bond activation of alkyl trifluoroacetates
Utsumi, Shinya,Katagiri, Toshimasa,Uneyama, Kenji
p. 84 - 89
(2013/11/06)
Cu-deposits on Mg metal surfaces promote electron transfer reactions
The enhancement of the electron transfer processes in the Grignard reagent formation-type ring silylation and the defluorination-silylation of perfluoroalkyl benzenes by Cu(0)-deposited Mg metal were confirmed. Microscopic analysis and substituent effects implied a different reduction process in the presence of Cu-deposited Mg metal than in the presence of bare Mg metal.
Utsumi, Shinya,Katagiri, Toshimasa,Uneyama, Kenji
experimental part
p. 1085 - 1091
(2012/03/07)
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