Trifluoromethanesulfonates of silicon, germanium, tin and lead are obtained by cleavage of the corresponding phenyl derivatives with CF3SO3H.Selective cleavage of the tin-carbon bond is observed in the case of silyl- and germylstannanes.Reaction of bis(trifluoromethanesulfonates) with lithiumorganic compounds leads to functional substituted triflate derivatives.
Uhlig, W.
p. 377 - 383
(2007/10/02)
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