Copper-Catalyzed SN2′-Selective Allylic Substitution Reaction of gem-Diborylalkanes
A Cu/(NHC)-catalyzed SN2′-selective substitution reaction of allylic electrophiles with gem-diborylalkanes is reported. Different substituted gem-diborylalkanes and allylic electrophiles can be employed in this reaction, and various synthetic v
Zhang, Zhen-Qi,Zhang, Ben,Lu, Xi,Liu, Jing-Hui,Lu, Xiao-Yu,Xiao, Bin,Fu, Yao
supporting information
p. 952 - 955
(2016/03/15)
Copper-Catalyzed SN2′-Selective Allylic Substitution Reaction of gem-Diborylalkanes
A Cu/(NHC)-catalyzed SN2′-selective substitution reaction of allylic electrophiles with gem-diborylalkanes is reported. Different substituted gem-diborylalkanes and allylic electrophiles can be employed in this reaction, and various synthetic valuable functional groups can be tolerated. The asymmetric version of this reaction was initially researched with chiral N-heterocyclic carbene (NHC) ligands.
Zhang, Zhen-Qi,Zhang, Ben,Lu, Xi,Liu, Jing-Hui,Lu, Xiao-Yu,Xiao, Bin,Fu, Yao
supporting information
p. 952 - 955
(2016/03/15)
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