Chemical communication: Conductors and insulators of screw-sense preference between helical oligo(aminoisobutyric acid) domains
1H NMR studies quantify the abilities of achiral amino acids to communicate a left-handed screw-sense preference from one helical Aib 4 domain to another: certain quaternary amino acids (e.g. Ac 6c) act as effective conductors of conformational preference while others (e.g. diphenylglycine) acts as insulators.
Boddaert, Thomas,Sola, Jordi,Helliwell, Madeleine,Clayden, Jonathan
p. 3397 - 3399
(2012/05/20)
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