136860-48-5Relevant articles and documents
Reactions of Cage Substrates with Sulfur Nucleophiles
Klimochkin, Yu. N.,Ivleva,Shiryaev
, p. 355 - 363 (2021/04/14)
Abstract: Reactions of alcohols of the adamantane series and adamantan-1-yl nitrates with sulfur nucleophiles in 94% sulfuric acid afforded a number of new sulfur-containing adamantane derivatives such as carbamo-thioates, isothiocyanates, and carbamodithioates. Di(adamantan-1-yl) disulfide was synthesized by reaction of admantan-1-yl nitrate with sodium sulfide nonahydrate in 94% sulfuric acid.