Sulfur-nitrogen and carbon-nitrogen bond formation by intermolecular imination and amidation without catalyst
Imination and amidation of sulfides, sulfoxides, and olefins using 4H-1,2,4-triazole-4-amine as a nitrogen source with PhI(OAc)2 as an oxidant were achieved in moderate to high yields without the addition of a catalyst. The carbon-nitrogen and