137219-34-2

Basic information

• Product Name: 9-FLUORENONE-D8
• Synonyms: 9-FLUORENONE-D8;1,2,3,4,5,6,7,8-octadeuteriofluoren-9-one
• CAS NO: 137219-34-2
• Molecular Formula: C13D8O
• Molecular Weight: 188.25
• Mol File: 137219-34-2.mol

Chemical Properties

• Appearance: /
• Storage Temp.: -20°C Freezer
• Solubility: Chloroform (Slightly), Methanol (Slightly)
• CAS DataBase Reference: 9-FLUORENONE-D8(CAS DataBase Reference)
• NIST Chemistry Reference: 9-FLUORENONE-D8(137219-34-2)
• EPA Substance Registry System: 9-FLUORENONE-D8(137219-34-2)

Safety Data

• Hazardous Substances Data: 137219-34-2(Hazardous Substances Data)

Usage

Uses

Used in Chemical Industry:
9-FLUORENONE-D8 is used as an initiator for visible-light cured resin systems, taking advantage of its photosensitizing properties to facilitate the curing process and enhance the performance of the final product.
Used in Research and Development:
As a labelled analogue, 9-FLUORENONE-D8 is utilized in research and development for studying the properties and effects of 9-Fluorenone, particularly in the context of its potential toxic effects on humans, such as causing DNA mutations. This allows for a better understanding of the compound's behavior and potential risks, leading to improved safety measures and more effective applications.

Upstream product

• 81103-79-9 9H-fluorene-d₁₀ 

Relevant articles and documents

Aromatic Diesel Emissions as a Function of Engine Conditions

The abundance and distribution of the alkyl homologues of polycyclic aromatic hydrocarbons (naphthalene, fluorene, phenanthrene, pyrene, fluoranthene and phenylnaphthalene) and oxygenated polycyclic aromatic hydrocarbons (naphthalenecarboxaldehydes, fluoren-9-one, biphenylcarboxaldehydes, phenanthrenecarboxaldehydes and thioxathen-9-one) in the organic extractables of particulates produced by a diesel engine are reported.Samples were obtained at three engine loads and at three fuel injection timing conditions.The concentrations of alkyl homologues of PAH and oxy-PAH on the particulates were found to decrease as cylinder exhaust temperature increased.The degree of alkylation for the most abundant homologue of these compounds increased by one to two carbons as the cylinder exhaust temperature was decreased.

Negative Ions Generated by Reactions with Oxygen in the Chemical Ionization Source

The methane negative ion chemical ionization (NICI) mass spectra of polycyclic aromatic hydrocarbons are usually dominated by molecular, M-. or M - H(1-) ions; however, ions resulting from additions to M have also been reported.Some of these ions have been observed at -., (1-), (1-) and -. and have been attributed to reactions with either oxygen-containing impurities in the buffer gas or alkyl radical species generated by ionization of a hydrocarbon buffer gas.In this study, the NICI spectra of fluorene, anthracene and fluoranthene were studied in detail using quadrupole and Fourier transform mass spectrometers.Spectra were acquired when reactive species such as oxygen, water, nitrous oxide and carbon dioxide were added to the nitrogen buffer gas.Experiments with deuterated methane were also carried out.These studies indicated that buffer gas impurities affect the NICI spectra; however, gas-phase ion-molecule reactions were not responsible for all of the observed products.In addition to electron- and ion-molecule reactions, ions were observed that resulted from wall-catalyzed oxidation reactions followed by electron capture.These reactions were enhanced by the addition of oxygen and elevated ion source temperatures.Depending upon the parent PAH structure, oxidation products such as ketones, quinones and anhydrides were formed.