Stereocontrol in palladium-catalyzed propargylic substitutions: Kinetic resolution to give enantioenriched 1,5-enynes and propargyl acetates
Kinetic resolution during the catalytic allyl-propargyl cross-coupling with chiral starting materials can be accomplished with a chiral palladium catalyst. These reactions offer ready access to enantiomerically enriched enyne products from simple, readily
Ardolino, Michael J.,Eno, Meredith S.,Morken, James P.
supporting information
p. 3413 - 3419
(2013/12/04)
Construction of 1,5-enynes by stereospecific Pd-catalyzed allyl-propargyl cross-couplings
The palladium-catalyzed cross-coupling of chiral propargyl acetates and allyl boronates delivers chiral 1,5-enynes with excellent levels of chirality transfer and can be applied across a broad range of substrates.
Ardolino, Michael J.,Morken, James P.
p. 8770 - 8773
(2012/07/02)
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