Asymmetric copper-catalyzed addition of grignard reagents to aryl alkyl ketones
Chiral tertiary alcohols: A copper(I) catalyst with a chiral ferrocenyl diphosphine ligand facilitates the additive-free 1,2-addition of readily available Grignard reagents to aromatic ketones, thus providing access to chiral tertiary alcohols with excellent yields and enantioselectivities. Copyright
Madduri, Ashoka V. R.,Harutyunyan, Syuzanna R.,Minnaard, Adriaan J.
supporting information; experimental part
p. 3164 - 3167
(2012/05/05)
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