REACTION OF DIALKOXYPHOSPHORYL- AND THIOPHOSPHORYLSULFENYL BROMIDES WITH DIAZO COMPOUNDS
Reaction of dialkoxyphosphoryl- and thiophosphorylsulfenyl bromides with diazocompounds leads to the insertion of methylene or substituted methylene groups at the S-Br bond of the sulfenylbromide.In the reaction of dialkoxyphosphorylsulfenyl bromides with ethyl diazoacetate, insertion of an ethoxycarbonyl group at the S-Br bond of the sulfenyl bromide is accompanied by phosphoryl/thiophosphoryl rearrangement.
Khaskin, B. A.,Torgasheva, N. A.,Ishmuratov, A. S.
p. 989 - 993
(2007/10/02)
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