In situ dearomatisation/alkylation of arylphosphane derivatives
The dearomatisation of aryldialkylphosphane-boranes and aryldialkylphosphane oxides under Birch reduction conditions, followed by treatment with reactive alkyl halides, provides the corresponding α-functionalised (cyclohexa-1,4-dien-3-yl)phosphane derivatives. This reaction offers a method of choice for the synthesis of bulky (cyclohexadienyl)phosphanes.
Stankevic, Marek,Wojcik, Karolina,Jaklinska, Magdalena,Pietrusiewicz, K. Michal
experimental part
p. 2521 - 2534
(2012/06/01)
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