Efficient synthesis of oxazoles by dirhodium(ii)-catalyzed reactions of styryl diazoacetate with oximes
An efficient one-step synthesis of multi-functionalized oxazole derivatives is achieved in high yield by dirhodium(ii)-catalyzed reactions of styryl diazoacetate with aryl oximes. This journal is
Xu, Xinfang,Zavalij, Peter Y.,Doyle, Michael P.,Hu, Wenhao
p. 11522 - 11524,3
(2012/12/12)
Substrate-dependent divergent outcomes from catalytic reactions of silyl-protected enol diazoacetates with nitrile oxides: Azabicyclo[3.1.0]hexanes or 5-arylaminofuran-2(3 H)-ones
Dirhodium(II)-catalyzed reactions of silyl-protected enol diazoacetates with nitrile oxides exhibit high nitrile oxide substituent dependence in the production rearrangement products via dipolar cycloaddition and either the Neber rearrangement or the Lossen rearrangement.
Xu, Xinfang,Shabashov, Dmitry,Zavalij, Peter Y.,Doyle, Michael P.
experimental part
p. 5313 - 5317
(2012/08/07)
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