Nonnatural amino acid synthesis by using carbon-hydrogen bond functionalization methodology
Taking direction well: Substituted phenylalanine derivatives were prepared by C-H bond functionalization (see scheme). The syntheses are highly convergent and employ an N-phthaloylalanine with a 2-thiomethylaniline directing group. The use of an 8-aminoquinoline directing group allows for the diarylation of methyl and the diastereoselective arylation of methylene groups. Copyright
Tran, Ly Dieu,Daugulis, Olafs
p. 5188 - 5191
(2012/07/27)
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