Diastereoselective Diels-Alder reactions between substituted 1,3-butadienes and N-α-methylbenzylmaleimide
The TiCl4 catalyzed reaction between 2-t-butyl-1,3-butadiene and N-α-methylbenzylmaleimide at -65°C affords diastereomeric Diels-Alder adducts in a 15:1 ratio. The structure of the major adduct was determined by x-ray.
Baldwin,Greenspan,Alaimo,McPhail
p. 5877 - 5880
(2007/10/02)
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