Nargenicin biosynthesis. Incorporation of polyketide chain elongation intermediates and support for a proposed intramolecular diels-alder cyclization
A series of proposed polyketide chain elongation intermediates has been synthesized as the N-acetylcysteamine (NAC) thioesters and incorporated into nargenicin (1) in 13C-labeled form by administration to both actively fermenting and resting cu
Cane, David E.,Tan, Weitian,Ott, Walter R.
p. 527 - 535
(2007/10/02)
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