Aminosilylene can be prepared by 254-nm photolysis of silyl azide isolated in an argon matrix at 12 K.Subsequent irradiation with wavelenghts > 300 nm yields silaisonitrile (3) and molecular hydrogen.This reaction may be reversed with 254-nm light. - Key Words: Hydrogen capture / Matrix isolation / Photochemistry / Aminosilylene
Maier, Guenter,Glatthaar, Joerg,Reisenauer, Hans Peter
p. 2403 - 2406
(2007/10/02)
Azido-silane compositions
Azido-containing silane compositions of matter useful as coupling agents in the production of polymer composite articles.
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(2008/06/13)
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