138489-24-4Relevant articles and documents
RADICAL β-FRAGMENTATION OF BICYCLOCARBINOLAMIDES: SYNTHESIS OF FIVE- AND EIGHT-MEMBERED CYCLIC IMIDES
Hernandez, Rosendo,Melian, Daniel,Prange, Thierry,Suarez, Ernesto
, p. 439 - 454 (2007/10/02)
The influence of 4-alkyl or 4-aryl substituents in the regioselectivity of the β-fragmentation of carbinolamidyl radicals generated from the corresponding carbinolamides (7-13) by irradiation with visible light in the presence of (diacetoxyiodo)benzene an
Daphniphyllum Alkaloids. 10. Classical Total Synthesis of Methyl Homodaphniphyllate
Heathcock, Clayton H.,Davidsen, Steven K.,Mills, Sander G.,Sanner, Mark A.
, p. 2531 - 2544 (2007/10/02)
Details for the first total synthesis of a Daphniphyllum alkaloid are presented.The synthesis required a total of 15 steps from the known keto acid 4 and followed the course 4 -> 10 -> 11 -> 16 -> 20 -> 24 -> 25 -> 27 -> 29 -> 36 -> 46 -> 47 -> 48 -> 49 -