- Catalytic enantioselective one-pot aminoborylation of aldehydes: A strategy for construction of nonracemic α-amino boronates
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We report a strategy for the conversion of aldehydes to enantiomerically enriched α-amino boronates through the intermediacy of in situ-generated silylimines. This transformation is brought about by Pt-catalyzed asymmetric addition of B2(pin)s
- Hong, Kai,Morken, James P.
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supporting information
p. 9252 - 9254
(2013/07/26)
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- On the Ti-TADDOLate-Catalyzed Diels-Alder Addition of 3-Butenoyl-1,3-oxazolidin-2-one to Cyclopentadiene. General Features of Ti-BINOLate- and Ti-TADDOLate-Mediated Reactions
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A systematic investigation of the enantioselective Diels-Alder addition of 3-butenoyl-1,3-oxazolidin-2-one to cyclopentadiene under the influence of catalytic amounts of dichloro-Ti complexes of α,α,α',α'-tetraaryl-1,3-dioxolane-4,5-dimethanols (TADDOLs)
- Seebach, Dieter,Dahinden, Robert,Marti, Roger E.,Beck, Albert K.,Plattner, Dietmar A.,Kuehnle, Florian N. M.
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p. 1788 - 1799
(2007/10/02)
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- Evidence for the importance of π-π attractive interactions in enantioselective Diels-Alder reactions chiral catalysts of type (RO)2TiCl2
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Reaction of diol 4 with Ti(O i-Pr)4 followed by SiCl4 results in formation of the Ti (IV) complex 5 which is an exceptionally effective catalyst for enantioselective Diels-Alder reactions. The origin of the high enantioselectivities
- Corey,Matsumura
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p. 6289 - 6292
(2007/10/02)
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