COBALT(II) CHLORIDE CATALYSED CONVERSION OF ALLYLIC ALCOHOLS TO REARRANGED ALLYLIC AMIDES
Secondary and tertiary allylic alcohols can be converted to the corresponding allylically rearranged amides and acetates in presence of a catalytic quantity of cobalt(II) chloride and acetic anhydride in acetonitrile.Tertiary alcohols undergo complete rearrangement whereas the secondary ones yield a mixture of regioisomers.
Nayyar, Naresh K.,Reddy, M. Madhava,Iqbal, Javed
p. 6965 - 6968
(2007/10/02)
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