N,N'-Bis--ethylene diamine (5), synthesized from racemic 1,2-anhydro-3-O-(o-ethoxyphenyl)-glycerol (1) and ethylene diamine (2) or N,N'-dibenzyl ethylene diamine (3) crystallized in two fractions with different melting points.Both of these analytically pure products gave identical two spot tl-chromatograms on achiral phases.Attempts were made to resolve the mixtures which proved to consist of configurative but not constitutive isomers.Optically pure products were synthesized from chiral precursors.
Kristen, H.,Wrubel, F.,Widuwild, H.,Luecke, L.
p. 545 - 554
(2007/10/02)
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