SPECIAL FEATURES OF THE CHEMISTRY OF HYDRAZIDES OF ACIDS OF TRIVALENT PHOSPHORUS
The chemical behavior of hydrazides of acids of trivalent phosphorus in reactions involving the addition of sulfur and alkylation is similar to that of the corresponding dialkylamides; however, they display considerably higher reactivity in alcoholysis reactins, including acid-catalyzed conversions.It has been established that 1,3-butylenephosphorous trimethylhydrazide exists in the form of two geometric isomers having trans configurations, which are distinguished by the spatial conformation of the phosphorinane ring.
Grachev, M. K.,Bekker, A. R.,Nifant'ev, E. E.
p. 1441 - 1446
(2007/10/02)
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