Stereoselective synthesis of monofluoroalkyl α,β-unsaturated ketones from allenyl carbinol esters mediated by gold and selectfluor
Allenyl carbinol ester 3 isomerizes to an E,Z mixture of the corresponding diene 2 in the presence of gold catalyst 4, but the resulting mixture yields monofluoroalkyl α,β-unsaturated ketone 1 with exclusive E selectivity and in high yields after reaction
Jin, Zhuang,Hidinger, Rachel S.,Xu, Bo,Hammond, Gerald B.
supporting information
p. 7725 - 7729
(2012/10/30)
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