Biosynthesis of Vitamin B12 : Stereochemistry of Transfer of a Hydride Equivalent from NADPH by Precorrin-6x Reductase
Deuterium labelling with NMR analysis demonstrates that the enzyme precorrin-6x reductase transfers HR from C-4 of the pyridine residue of NADPH as the first step in the sequence leading from precorrin-6x to hydrogenobyrinic acid.
Kiuchi, Fumiyuki,Thibaut, Denis,Debussche, Laurent,Leeper, Finian J.,Blanche, Francis,Battersby, Alan R.
p. 306 - 308
(2007/10/02)
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