13994-39-3Relevant articles and documents
SYNTHESIS, REACTIVITY AND STRUCTURE OF NITRODIAZOACETIC ACID
O'Bannon, P. E.,Carroll, Patrick J.,Dailey, William P.
, p. 6031 - 6032 (1988)
Nitrodiazoacetic acid was prepared and its structure determined by low temperature X-ray crystallography.There is good agreement between the experimentally determined structure and that calculated at the ab initio rhf/3-21G level of theory.The acid is stable in neat trifluoroacetic acid and less stable in neutral non-polar solutions.In neutral polar solutions it undergoes rapid decarboxylation to yield nitrodiazomethane.
NITROCYCLOPROPANES FROM NITRODIAZOMETHANES. PREPARATION AND REACTIVITY
O'Bannon, P. E.,Dailey, William P.
, p. 7341 - 7358 (2007/10/02)
Nitrodiazo compounds cyclopropanate electron rich alkenes in the presence of rhodium(II) acetate.The yields and diastereoselectivities are dependent on both the alkene and the nitrodiazo precursor.Nitrocyclopropanecarboxylates undergo ring opening, reduct
THE SYNTHESIS OF NITROCYCLOPROPANES FROM NITRODIAZOMETHANES
O'Bannon, P. E.,Dailey, William P.
, p. 4197 - 4200 (2007/10/02)
The synthesis of novel 1-substituted nitrocyclopropanes using the rhodium(II) acetate catalyzed cyclopropanation reaction of several nitrodiazomethanes with electron rich alkenes is described.
