REACTION OF BISSILYLACETYLENES WITH HYDROGEN CHLORIDE
Reaction of bissilylacetylenes MenCl3-nSiCCSiMenCl3-n (where n = 0-3) with hydrogen chloride in the presence of ferric chloride gives stable adducts in a 1:1 ratio only for MeCl2Si and Me2ClSi derivatives.The tendency of 1,2-bissilylchloroethylenes MenCl3-nSiCH=CClSiMenCl3-n (where n = 1-3) to undergo breakdown under the action of FeCl3 is determined by the nature of the silyl groups and increases in the order MeCl2Si Me2ClSi Me3Si.
Lakhtin, V. G.,Sheludyakov, V. D.,Timofeev, V. S.,Bochkarev, V. N.,Slyusarenko, T. F.,Nosova, V. M.
p. 74 - 78
(2007/10/02)
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